UV/Vis+ Photochemistry Database
Literature Service: Organic Oxy/Peroxy Compounds I
Substances (unsorted): CH3O, CH3O2, CH3CHOO, (CH3)2COO, CH3CH2CHOO, C2H5O, C2H5O3, C2H5O2, n-C3H7O2, i-C3H7O2, C4H6O2, t-C4H9O2, neo-C5H11O2, c-C5H9O2, c-C6H11O2, CH3C(O)O2, HOCH2CH2O2, CH3C(O)CH2O2, C2H3O2
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| Authors | Journal/Source | Title/Paper | Data Sheet |
|---|---|---|---|
| CH3O; methoxy radical; methyloxidanyl; CAS-No.: 2143-68-2 | |||
| J. Liu, M.-W. Chen, D. Melnik, J.T. Yi, T.A. Miller | J. Chem. Phys., 130, 074302, (2009) | The spectroscopic characterization of the methoxy radical. I. Rotationally resolved A2 A1-X 2E electronic spectra of CH3O |
|
| X. Tang, X. Lin, G.A. Garcia, J.-C. Loison, C. Fittschen, X. Gu, W. Zhang, L. Nahon | J. Chem. Phys., 153, 031101, (2020) | Threshold photoelectron spectroscopy of the methoxy radical |
|
| CH3O2; methylperoxy radical; methyldioxy; CAS-No.: 2143-58-0; PubChem: CID 123144 | |||
| D.A. Parkes, D.M. Paul, C.P. Quinn, R.C. Robson | Chem. Phys. Lett., 23, 425-429, (1973) | The ultraviolet absorption by alkylperoxy radicals and their mutual reactions |
|
| B. Hickel | J. Phys. Chem., 79 (11), 1054-1059, (1975) | Absorption spectra and kinetics of methyl and ethyl radicals in water |
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| D.A. Parkes | Int. J. Chem. Kin., 9, 451-469, (1976) | The oxidation of methyl radicals at room temperature |
|
| C.J. Hochanadel, J.A. Ghormley, J.W. Boyle, P.J. Ogren | J. Phys. Chem., 81, 3-7, (1977) | Absorption spectrum and rates of formation and decay of the CH3O2 radical |
|
| C. Anastasi, I.W.M. Smith, D.A. Parkes | J. Chem. Soc. Faraday Trans., 74, 1693-1701, (1978) | Flash photolysis study of the spectra of CH3O2 and C(CH3)3O2 radicals and the kinetics of their mutual reactions with NO |
|
| C.S. Kan, J.G. Calvert | Chem. Phys. Lett., 63, 111-114, (1979) | Water vapor dependence of the kinetics of the CH3O2—CH3O2 reaction |
|
| R.A. Cox, G.S. Tyndall | Chem. Phys. Lett., 65, 357-360, (1979) | Rate constants for reactions of CH3O2 in the gas phase |
|
| H. Adachi, N. Basco, D.G.L. James | Int. J. Chem. Kinetics, 12, 949-977, (1980) | Mutual interactions of the methyl and methylperoxy radicals studied by flash photolysis and kinetic spectroscopy |
|
| S.P. Sander, R.T. Watson | J. Phys. Chem., 84, 1664-1674, (1980) | Kinetics studies of the reactions of CH3O2 with NO, NO2, and CH3O2 at 298 K |
|
| M.J. Pilling, M.J.C. Smith | J. Phys. Chem., 89, 4713-4720, (1985) | A laser flash photolysis study of the reaction CH3 + O2 --> CH3O2 at 298 K |
|
| K. McAdam, B. Veyret, R. Lesclaux | Chem. Phys. Lett., 133, 39-44, (1987) | UV absorption spectra of HO2 and CH3O2 radicals and the kinetics of their mutual reactions at 298 K |
|
| M.J. Kurylo, T.J. Wallington, P.A. Ouellette | J. Photochemistry, 39, 201-215, (1987) | Measurements of the UV absorption cross-sections for HO2 and CH3O2 in the gas phase |
|
| T.J. Wallington, P. Dagaut, M.J. Kurylo | J. Photochem. Photobiol. A: Chemistry, 42, 173-185, (1988) | Measurements of the gas phase UV absorption spectrum of C2H5O2 radicals and of the temperature dependence of the rate constant for their self-reaction |
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| M.E. Jenkin, R.A. Cox, G.D. Hayman, L.J. Whyte | J. Chem. Soc., Faraday Trans. 2, 84, 913-930, (1988) | Kinetic study of the reactions CH3O2 + CH3O2 and CH3O2 + HO2 using molecular modulation spectroscopy |
|
| G. Moortgat, B. Veyret, R. Lesclaux | J. Phys. Chem., 93, 2362-2368, (1989) | Absorption spectrum and kinetics of reactions of the acetylperoxy radical |
|
| F.-G. Simon, W. Schneider, G.K. Moortgat | Int. J. Chem. Kinetics, 22, 791-813, (1990) | UV-Absorption spectrum of the methylperoxy radical and the kinetics of its disproportionation reaction at 300 K |
|
| P. Dagaut, M.J. Kurylo | J. Photochem. Photobiol. A: Chem., 51, 133-140, (1990) | The gas phase UV absorption spectrum of CH3O2 radicals: A reinvestigation |
|
| P.D. Lightfoot, B. Veyret, R. Lesclaux | J. Phys. Chem., 94 (2), 708-714, (1990) | Flash photolysis study of the methylperoxy + hydroperoxy reaction between 248 and 573 K |
|
| M.E. Jenkin, R.A. Cox | J. Phys. Chem., 95, 8, 3229–3237, (1991) | Kinetics of reactions of methylperoxy and 2-hydroxyethylperoxy radicals produced by the photolysis of iodomethane and 2-iodoethanol |
|
| M.M. Maricq, T.J. Wallington | J. Phys. Chem., 96, 986-992, (1992) | Absolute ultraviolet cross sections of methyl and ethyl peroxy radicals |
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| P.D. Lightfoot, R.A. Cox, J.N. Crowley, M. Destriau, G.D. Hayman, M.E. Jenkin, G.K. Moortgat, F. Zabel | CEC, Air Pollution Report 40, (1993) | Organic Peroxy Radicals: Kinetics, spectroscopy and tropospheric chemistry |
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| C.M. Roehl, D. Bauer, G.K. Moortgat | J. Phys. Chem., 100, 4038-4047, (1996) | Absorption spectrum and kinetics of the acetylperoxy radical |
|
| A. Fahr, A.H. Laufer, M. Krauss, R. Osman | J. Phys. Chem. A, 101, 4879-4886, (1997) | Gas Phase Absorption Spectrum and Cross Sections of Vinylperoxy (C2H3O2) Radical |
|
| O.J. Nielsen, M.S. Johnson, T.J. Wallington, L.K. Christensen, J. Platz | Int. J. Chem. Kinetics, 34, 283-291, (2002) | UV absorption spectra of HO2, CH3O2, C2H5O2, and CH3C(O)CH2O2 radicals and mechanism of the reactions of F and Cl atoms with CH3C(O)CH3 |
|
| D.B. Atkinson, J.L. Spillman | J. Phys. Chem. A, 106, 8891-8902, (2002) | Alkylperoxy radical kinetics measured using near-infrared CW-cavity ring-down spectroscopy |
|
| X. Tang, X. Gu, X. Lin, W. Zhang, G.A. Garcia, C. Fittschen, J.-C. Loison, K. Voronova, B. Sztaray, L. Nahon | J. Chem. Phys., 152, 104301, (2020) | Vacuum ultraviolet photodynamics of the methyl peroxy radical studied by double imaging photoelectron photoion coincidences |
|
| C2H4O2; CH3CHOO; methyl carbonyl oxide; CAS-No.: | |||
| J.M. Beames, F. Liu, L. Lu, M.I. Lester | J. Chem. Phys., 138, 244307, (2013) | UV spectroscopic characterization of an alkyl substituted Criegee intermediate CH3CHOO |
|
| M.C. Smith, W.-L. Ting, C.-H. Chang, K. Takahashi, K.A. Boering, J. Jr-Min Lin | J. Chem. Phys., 141, 074302, (2014) | UV absorption spectrum of the C2 Criegee intermediate CH3CHOO |
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| C3H6O2; (CH3)2COO; dimethyl carbonyl oxide; CAS-No.: | |||
| F. Liu, J.M. Beames, A.M. Green, M.I. Lester | J. Phys. Chem. A, 118 (12), 2298-2306, (2014) | UV Spectroscopic Characterization of Dimethyl- and Ethyl-Substituted Carbonyl Oxides |
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| Y.-P. Chang, C.-H. Chang, K. Takahashi, J. Jr-M. Lin | Chem. Phys. Lett., 653, 155-160, (2016) | Absolute UV absorption cross sections of dimethyl substituted Criegee intermediate (CH3)2COO |
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| C3H6O2; CH3CH2CHOO; ethyl carbonyl oxide; CAS-No.: | |||
| F. Liu, J.M. Beames, A.M. Green, M.I. Lester | J. Phys. Chem. A, 118 (12), 2298-2306, (2014) | UV Spectroscopic Characterization of Dimethyl- and Ethyl-Substituted Carbonyl Oxides |
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| C2H5O; CH3OCH2; methoxymethyl radical; CAS-No.: 16520-04-0 | |||
| S. Langer, E. Ljungström, T. Ellermann, O.J. Nielsen, J. Sehested | Chem. Phys. Lett., 240, 53-56, (1995) | UV absorption spectrum of CH3OCH2 radicals and kinetics of the reaction of CH3OCH2O2 radicals with NO and NO2 in the gas phase |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| R. Liu, M.M. Maricq, Y. Li, J.S. Francisco | J. Chem. Phys., 110, (9), 4410-4412, (1999) | Ab initio study of the electronic spectrum of the CH3OCH2 radical |
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| C2H5O2; ethyl peroxy radical; ethyldioxy; CAS-No.: 3170-61-4; PubChem: CID 123182 | |||
| B. Hickel | J. Phys. Chem., 79 (11), 1054-1059, (1975) | Absorption spectra and kinetics of methyl and ethyl radicals in water |
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| J. Munk, P. Pagsberg, E. Ratajczak, A. Sillesen | J. Phys. Chem., 90, 2752-2757, (1986) | Spectrokinetic studies of ethyl and ethylperoxy radicals |
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| F.C. Cattell, J. Cavanagh, R.A. Cox, M.E. Jenkin | J. Chem. Soc., Faraday Trans., 2, 82, 1999 - 2018, (1986) | A kinetics study of reactions of HO2 and C2H5O2 using diode laser absorption spectroscopy |
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| H. Adachi, N. Basco, D.G.L. James | Int. J. Chem. Kinetics, 11, 1211-1229, (1979) | The ethylperoxy radical spectrum and rate constant for mutual interaction measured by flash photolysis and kinetic spectroscopy |
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| T.J. Wallington, P. Dagaut, M.J. Kurylo | J. Photochem. Photobiol. A: Chem., 42, 173-185, (1988) | Measurements of the gas phase UV absorption spectrum of C2H5O2· radicals and of the temperature dependence of the rate constant for their self-reaction |
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| D. Bauer, J.N. Crowley, G.K. Moortgat | J. Photochem. Photobiol. A: Chem., 65, 329-344, (1992) | The UV absorption spectrum of the ethylperoxy radical and its self-reaction kinetics between 218 and 333 K |
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| M.M. Maricq, T.J. Wallington | J. Phys. Chem., 96, 986-992, (1992) | Absolute ultraviolet cross sections of methyl and ethyl peroxy radicals |
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| F.F. Fenter, V. Catoire, R. Lesclaux, P.D. Lightfoot | J. Phys. Chem., 97, 3530-3538, (1993) | The ethylperoxy radical : its ultraviolet spectrum, self-reaction, and reaction with HO2, each studied as a function of temperature |
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| O.J. Nielsen, M.S. Johnson, T.J. Wallington, L.K. Christensen, J. Platz | Int. J. Chem. Kinetics, 34, 283-291, (2002) | UV absorption spectra of HO2, CH3O2, C2H5O2, and CH3C(O)CH2O2 radicals and mechanism of the reactions of F and Cl atoms with CH3C(O)CH3 |
|
| D.B. Atkinson, J.L. Spillman | J. Phys. Chem. A, 106, 8891-8902, (2002) | Alkylperoxy radical kinetics measured using near-infrared CW-cavity ring-down spectroscopy |
|
| D. Melnik, R. Chhantyal-Pun, T.A. Miller | J. Phys. Chem. A, 114 (43), 11583-11594, (2010) | Measurements of the Absolute Absorption Cross Sections of the A* <-- X Transition in Organic Peroxy Radicals by Dual-Wavelength Cavity Ring-Down Spectroscopy |
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| Z. Wen, X. Lin, X. Tang, B. Long, C. Wang, C. Zhang, C. Fittschen, J. Yang, W. Zhang | Phys. Chem. Chem. Phys., 23, 22096-22102, (2021) | Vacuum ultraviolet photochemistry of the conformers of the ethyl peroxy radical |
|
| n-C3H7O2; n-propyl peroxy radical; propyldioxy; CAS-No.: 42953-38-8; PubChem: CID 181742 | |||
| H. Adachi, N. Basco | Int. J. Chem. Kinetics, 14, 1125-1138, (1982) | Spectra of propylperoxy radicals and rate constants for mutual interaction |
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| S.J. Zalyubovsky, B.G. Glover, T.A. Miller, C. Hayes, J.K. Merle, C.M. Hadad | J. Phys. Chem. A, 109, 1308-1315, (2005) | Observation of the ˜A - ˜X Electronic Transition of the 1-C3H7O2 and 2-C3H7O2 Radicals Using Cavity Ringdown Spectroscopy |
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| X. Tang, X. Lin, G.A. Garcia, J.-C. Loison, Z. Gouid, H.H. Abdallah, C. Fittschen, M. Hochlaf, X. Gu, W. Zhang, L. Nahon | Chemical Communications, 56, 15525-15528, (2020) | Identifying isomers of peroxy radicals in the gas phase: 1-C3H7O2 vs. 2-C3H7O2 |
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| C2H5O3; CH3OCH2O2; methoxymethylperoxy radical; CAS-No.: 73526-16-6; PubChem: CID 156004 | |||
| P. Dagaut, T.J. Wallington, M.J. Kurylo | J. Photochem. Photobiol. A: Chem., 48, 187-198, (1989) | Gas phase studies of substituted methylperoxy radicals: The UV absorption spectrum and self-reaction kinetics of CH3OCH2O2 - The reaction of CF2ClO2 with Cl atoms |
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| M.E. Jenkin, G.D. Hayman, T.J. Wallington, M.D. Hurley, J.C. Ball, O.J. Nielsen, T. Ellermann | J. Phys. Chem., 97, 45, 11712–11723, (1993) | Kinetic and mechanistic study of the self reaction of CH3OCH2O2 radicals at room temperature |
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| i-C3H7O2; n-propyl peroxy radical | |||
| H. Adachi, N. Basco | Int. J. Chem. Kinetics, 14, 1125-1138, (1982) | Spectra of propylperoxy radicals and rate constants for mutual interaction |
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| J. Munk, P. Pagsberg, E. Ratajczak, A. Sillesen | Chem. Phys. Lett., 132, 417-421, (1986) | Spectrokinetic studies of i-C3H7 and i-C3H7O2 radicals |
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| related data (quantum yield studies; photolysis studies, etc.) | |||
| G. Chettur, A. Snelson | J. Phys. Chem., 91, 913-919, (1987) | Alkylperoxy and alkyl radicals. 3. Infrared spectra and ultraviolet photolysis of i-C3H7O2 and i-C3H7 radicals in Argon + Oxygen matrices |
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| C4H6O2; methacrolein oxide; CAS-No.: | |||
| M.F. Vansco, B. Marchetti, N. Trongsiriwat, T. Bhagde, G. Wang, P.J. Walsh, S.J. Klippenstein, M.I. Lester | J. Am. Chem. Soc., 141, 38, 15058–15069, (2019) | Synthesis, electronic spectroscopy, and photochemistry of methacrolein oxide: A four-carbon unsaturated Criegee intermediate from isoprene ozonolysis |
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| C4H6O2; methyl vinyl ketone oxide; CAS-No.: | |||
| M.F. Vansco, B. Marchetti, M.I. Lester | J. Chem. Phys., 149, 244309, (2018) | Electronic spectroscopy of methyl vinyl ketone oxide: A four-carbon unsaturated Criegee intermediate from isoprene ozonolysis |
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| t- C4H9O2; t-butyl peroxy radical | |||
| D.A. Parkes | Proc. 15th Int. Symp. Combustion, 795-805, (1975) | The roles of alkylperoxy alkoxy radicals in alky radical oxidation at room temperature |
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| D.A. Parkes, L.J. Kirsch | priv. comm., (1978) | absorption cross sections of t-butyl peroxy radical |
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| C. Anastasi, I.W.M. Smith, D.A. Parkes | J. Chem. Soc. Faraday Trans., 74, 1693-1701, (1978) | Flash photolysis study of the spectra of CH3O2 and C(CH3)3O2 radicals and the kinetics of their mutual reactions with NO |
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| P.D. Lightfoot, P. Roussel, B. Veyret, R. Lesclaux | J. Chem. Soc. Faraday Trans., 84, 2927-2936, (1990) | Flash photolysis study of the spectra and self-reactions of neopentylperoxy and t-butylperoxy radicals |
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| neo-C5H11O2; neo-pentyl peroxy radical | |||
| P.D. Lightfoot, P. Roussel, B. Veyret, R. Lesclaux | J. Chem. Soc. Faraday Trans., 84, 2927-2936, (1990) | Flash photolysis study of the spectra and self-reactions of neopentylperoxy and t-butylperoxy radicals |
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| P. Dagaut, M.J. Kurylo | Int. J. Chem. Kinetics, 22, 1177-1187, (1990) | A flash photolysis investigation of the gas phase uv absorption spectrum and self-reaction kinetics of the neopentylperoxy radical |
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| T.J. Wallington, J.M. Andino, A.R. Potts, O.J. Nielsen | Int. J. Chem. Kinetics, 24 (7), 649-663, (1992) | Pulse radiolysis and fourier transform infrared study of neopentyl peroxy radicals in the gas phase at 297 K |
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| c-C5H9O2; cyclopentyl peroxy radical | |||
| D.M. Rowley, P.D. Lightfoot, R. Lesclaux, T.J. Wallington | J. Chem. Soc. Faraday Trans., 88, 1369, (1992) | The UV absorption spectrum and self reaction of cyclopentyl peroxy radicals |
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| c-C6H11O2; cyclohexyl peroxy radical | |||
| D.M. Rowley, P.D. Lightfoot, R. Lesclaux, T.D. Wallington | J. Chem. Soc. Faraday Trans., 87, 3221-3226, (1991) | UV spectrum and self-reaction kinetics of the cyclohexylperoxy radical |
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| C2H3O3; CH3C(O)O2; acetyl peroxy radical | |||
| M.C. Addison, J.J. Burrows, R.A. Cox, R. Patrick | Chem. Phys. Lett., 73, 283-287, (1980) | Absorption spectrum and kinetics of the acetylperoxy radical |
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| N. Basco, S.S. Parmar | Int. J. Chem. Kinetics, 17, 891-900, (1985) | Spectra and reactions of acetyl and acetylperoxy radicals |
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| G. Moortgat, B. Veyret, R. Leclaux | J. Phys. Chem., 93, 2362-2368, (1989) | Absorption spectrum and kinetics of reactions of the acetylperoxy radical |
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| C.M. Roehl, D. Bauer, G.K. Moortgat | J. Phys. Chem., 100 (10), 4038-4047, (1996) | Absorption Spectrum and Kinetics of the Acetylperoxy Radical |
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| M.M. Maricq, J.J. Szente | J. Phys. Chem., 100, 4507-4513, (1996) | The CH3C(O)O2 radical. Its UV spectrum, self-reaction kinetics, and reaction with CH3O2 |
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| M. Rolletter, E.Assaf, M. Assali, H. Fuchs, C. Fittschen | J. Quant. Spectr. Rad. Transfer, 245, 106877, (2020) | The Absorption Spectrum and Absolute Absorption Cross Sections of Acetylperoxy Radicals, CH3C(O)O2 in the near IR |
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| C2H5O3; HOCH2CH2O2; hydroxyethyl peroxy radical | |||
| M.E. Jenkin, R.A. Cox | J. Phys. Chem., 95, 3229-3237, (1991) | Kinetics of reactions of CH3O2 and HOCH2CH2O2 radicals produced by the photolysis of iodomethane and 2-iodoethanol |
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| C. Anastasi, D.J. Muir, V.J. Simpson, P. Pagsberg | J. Phys. Chem., 95, 5791-5797, (1991) | Spectrum and mutual kinetics of HOCH2CH2O2 radicals |
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| T.P. Murrells, M.E. Jenkin, S.J. Shalliker, G.D. Hayman | J. Chem. Soc. Faraday Trans., 87, 2351-2360, (1991) | Laser flash photolysis study of the UV spectrum and kinetics of reactions of HOCH2CH2O2 radicals |
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| C3H5O3; CH3C(O)CH2O2; acetonyl peroxy radical | |||
| R.A. Cox, J. Munk, O.J. Nielsen, P. Pagsberg, E. Ratajczak | Chem. Phys. Lett., 173, 206-210, (1990) | Ultraviolet absorption spectra and kinetics of acetonyl and acetonylperoxy radicals |
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| O.J. Nielsen, M.S. Johnson, T.J. Wallington, L.K. Christensen, J. Platz | Int. J. Chem. Kinetics, 34, 283-291, (2002) | UV absorption spectra of HO2, CH3O2, C2H5O2, and CH3C(O)CH2O2 radicals and mechanism of the reactions of F and Cl atoms with CH3C(O)CH3 |
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| C2H3O2; vinylperoxy radical | |||
| A. Fahr, A.H. Laufer, M. Krauss, R. Osman | J. Phys. Chem. A, 101, 4879-4886, (1997) | Gas Phase Absorption Spectrum and Cross Sections of Vinylperoxy (C2H3O2) Radical |
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